SERDP 2016 Project-of-the-Year Award goes to two MSD faculty

Craig Tobias and Penny Vlahos win the SERDP 2016 Project-of-the-Year award for their work in studying the impact of munitions compounds in marine and estuarine ecosystems.

Read more about the project and the award here:

Emily Seelen spending nine months in Sweden to study the bioavailability of methylmercury using a molecular approach

Emily Seelen, a graduate student with Robert Mason who has a NSF Graduate Fellowship, was recently awarded a GROW (Graduate Research Opportunities Worldwide) fellowship to spend nine months working with Dr. Erik Björn at the University of Umeå in Sweden. Emily left in October to begin her study: “A molecular approach to understanding the bioavailability of methylmercury associated with various sources of natural dissolved organic matter (DOM)”. The focus is on coastal and oceanic DOM interaction with methylmercury, which has been studied very little relative to its interaction with other DOM pools. Emily’s research will involve the use of high resolution instrumentation to characterize the DOM and it’s methylmercury binding capacity including x-ray near edge adsorption structure spectroscopy, Orbitrap LC-MS, and other related approaches. Emily has been a NSF Graduate Fellow since July 2013.
Image: Emily extracting organic matter from water samples for her studies in Sweden.
seelen in lab

NOAA announces funding for research on sand lance

The Ocean & Atmospheric Research program (OAR) of NOAA and Sea Grant just announced the winners of its most recent round of research funding to better understand the consequences of ocean warming and acidification on key marine resources in U.S. Northeast coastal waters. Hannes Baumann and collaborators were happy and proud to learn that their proposed work on the climate sensitivity of Northern sand lance (Ammodytes dubius) was one of the four projects selected for funding. This is particularly good news for Chris Murray, who for his PhD can now expand his experimental rearing expertise to this important species.
This project will be conducted collaboratively with colleagues from NOAA (David Wiley), USGS (Page Valentine), Boston University (Les Kaufman), and Woods Hole Oceanographic Institution (Scott Gallager).

You can read the official announcement as it appeared on 6 September 2016 on NOAA’s News site

DMS graduate student Vena Haynes awarded EPA STAR Fellowship

Vena Haynes was recently awarded the EPA STAR Fellowship for her environmental toxicology research with Dr. J. Evan Ward. Vena is a PhD student in the UConn Marine Sciences program, where her research is focused on the effects of environmental pollutants on marine food webs. Manufactured nanomaterials are entering aquatic environments from product usage, industrial waste, and wastewater treatment plant effluents. Specifically, titanium dioxide nanoparticles found in consumer products, such as sunscreen and personal care products, can be toxic to organisms and its toxicity can increase with exposure to light. Very little research has been done on the effects of these nanoparticles in the marine environment with exposure to natural light. The objective of this project is to examine the effects of titanium dioxide nanoparticles on ecologically important food web grazers that inhabit coastal waters, using environmentally relevant experimental conditions. This work will aid in the development of safer nanomaterials and help predict impacts on grazer populations and organisms that rely on grazers for food (primarily fish).



Marine Sciences Alumni Chris Perkins captures stunning images of great whites!

The smile that says ‘I’d like to eat you!’ Photographer captures terrifying close-up of great white shark’s teeth as he comes face-to-face with deadly predator.

There can be few more terrifying sights in the world than a shark grinning greedily at you.

But American marine biologist Chris Perkins has captured the underwater predator in all its glory in a series of stunning images.

The stillness of the water gives an eerie insight into the stealth these apex predators use when breaching the ocean waves in search of their next meal.

Read more here!

Dimethylmercury in the Ocean: Where does it come from?

press release

The accumulation of mercury, primarily as methylmercury, into fish and seafood consumed by humans is a global health concern. Recent research has highlighted the potential sources of methylmercury in the ocean, and demonstrated that it can be formed by microbial methylation of inorganic mercury. However, one of its sources could also be the degradation of dimethylmercury. There has been little study, however, of the formation pathways of dimethylmercury in the ocean, even though it has been detected in surface and deep waters.

A new paper published in Nature Scientific Reports (  by researchers in the Department of Marine Sciences (DMS) at the University of Connecticut has shed light on potential pathways for its formation, and suggests that dimethylmercury may be formed by abiotic processes from methylmercury. These studies were carried out by research scientist Sofi Jonsson and graduate student Nashaat Mazrui in Robert Mason’s laboratory. Their experiments show that dimethylmercury can be formed in the presence of iron sulfide particles, as well as other metal sulfide particles, via the reaction of two methylmercury molecules bound to the particle surface. The products of the reaction are dimethylmercury and inorganic mercury, which is precipitated onto the surface. In addition, these reactions were also shown to occur in the presence of organic compounds with reduced sulfur groups (thiols). The proximity of the bound methylmercury molecules determines the rate of the reaction, and the reaction is more favorable with organic compounds with multiple thiols.

“The reaction pathways are highly favorable and we were able to show that the reactions occur under a wide variety of conditions” said Jonsson “and our calculations suggest that these mechanisms could account for much of the dimethylmercury in the ocean.”  Mason commented that recent estimates suggest that about half the methylmercury formed in the upper ocean is from the degradation of dimethylmercury, and that further studies are needed to examine the importance of the proposed pathway compared to other mechanisms. The authors suggest that such reactions could be occurring within particles in the ocean, or within microbial cells. It is also possible that the reactions could occur on the surface of nanoparticles and Mason’s group, in collaboration with Jing Zhao at the Department of Chemistry (UConn), will further explore this possibility by studying these reactions on both natural and manufactured nanoparticles, and the factors that influence the reaction rate.

Early measurements of dimethylmercury in the equatorial Pacific Ocean were made by Jon Kim and Robert Mason, while graduate students at DMS, and many other studies have reported its presence in ocean waters since then.  One place where dimethylmercury has been measured in higher concentrations is the Arctic and a recent modeling paper by researchers at Harvard suggests that a large fraction of the methylmercury produced in the Arctic is converted to dimethylmercury. Although the paper published from researchers at Harvard does not propose a mechanism for this reaction, it could involve the reactions proposed on particle surfaces in the water or sediment. Jonsson will later this summer participate in a research expedition in the Arctic onboard the Swedish icebreaker Oden which will allow her to test some of the ideas about formation and stability of dimethylmercury in this region.

press release